TheWoWDBI found this version of Baroness Vashj at the Seat of the Primus in Maldraxxus at 46.6, 38.1 after completing The Door to the Unknown. If you click on Vashj to speak with her, she will tell you more about her thoughts on the afterlife.
"I had always imagined the afterlife would be extravagant and beautiful--a realm all my own where I could dote and be doted on.
Imagine my surprise when I arrived in a necrotic wasteland more barren than Outland and more hostile than the crushing depths...
Imagine my surprise when I liked it.
This fight for dominance is more exhilarating than any luxuries could ever be."
Elite
Baroness Vashj
Matron of Spies
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Details
This roster comes from the current game client's data files, so it is not a complete list of every NPC in the game - older world NPCs that are no longer in the modern client are absent.
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Level and Map Tracking
The game data tunes Baroness Vashj for level 60, Shadowlands content.
The map marks it with vignette 4,249.