The August Celestials

A rather hard faction to grind, although the only thing granting you rep are the dailies. Its one that must be obtainable for those that want to ride Alani after spending hours and hours of killing mobs to obtain the legendary somehow Skyshards which have a low drop rate

From what I've gathered from the wealth of information other wonderful people have added onto wowhead about the August Celestials, the quest "A Celestial Task" can be obtained at friendly with the Golden Lotus. You cannot start doing dailies with the August Celestials, however, until you reach revered with the Golden Lotus. If you search wowhead for August Celestials, and then choose faction instead of acheivement, there's a lot of great input about quest chains and details about the faction itself such as items and reputation obtained, etc.

Edit: Daily quests for the August Celestials are picked up at the quest hub underneath the Terrace of your faction's Shrine.

Killing Celestial guards on Timeless Isle will reduce your reputation with August Celestials if you're on a PvE realm.