Suns Out, Thori'dals Out

As of 7.2, tokens can be clicked to automatically create the item based on your loot specialization, bypassing the need to visit a tier vendor.

These tokens "of the Forgotten" can be turned in for 3-(unmatching-)pieces of the Tier 6 PvE set (subsequent to the original 5-piece set which has its own achievement here) or level 70 PvP armor. All tokens come from [zone=4075].

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• PvE: find [npc=25976] hovering around a map on a ship in Sun's Reach Harbor on the Isle of Quel'Danas.
• 
  
• PvP: [npc=26089] is on the upper level of the Sun's Reach Armory on the Isle of Quel'Danas.
• 
  

Tokens are separated by class into 3 groups (this tier is not available for death knights, monks, or demon hunters):

• Conqueror: Paladin / Priest / Warlock
• 
  
• Protector: Warrior / Hunter / Shaman
• 
  
• Vanquisher: Rogue / Mage / Druid
• 
  

Bracers - [npc=24892] or the Eredar Twins

[item=34848]
[item=34851]
[item=34852]

Belt - [npc=24882] or the Eredar Twins

[item=34853]
[item=34854]
[item=34855]

Boots - [npc=25038] or the Eredar Twins

[item=34856]
[item=34857]
[item=34858]

Other pieces?

You need more than the 3 supplemental pieces for this achievement, but the rest of Tier 6 counts for the Black Temple achievement. I'm investigating if you need everything listed in the Sunwell set in the new appearance/set tab, or if it's a % of what's listed. Testing is RNG-dependent.

• The Eredar Twins are the 4th encounter in the Sunwell: [npc=25166] & Lady Sacrolash. The twins randomly drop one of the above tokens.

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Criteria of the meta Azeroth's Next Top Model, wowhead wrote up a full guide for the pve sets here.

Part of Azeroth's Next Top Model.
The pieces of these sets drop in [zone=4075].

1. 
   
2. [class=6]: n/a
3. Death Knight
   
4. [class=12]: n/a
5. Demon Hunter
   
6. [class=11]: [transmog-set=417]
7. Druid
   
8. [class=3]: [transmog-set=418]
9. Hunter
   
10. [class=8]: [transmog-set=415]
11. Mage
    
12. [class=10]: n/a
13. Monk
    
14. [class=2]: [transmog-set=420]
15. Paladin
    
16. [class=5]: [transmog-set=414]
17. Priest
    
18. [class=4]: [transmog-set=416]
19. Rogue
    
20. [class=7]: [transmog-set=419]
21. Shaman
    
22. [class=9]: [transmog-set=413]
23. Warlock
    
24. [class=1]: [transmog-set=421]
25. Warrior
    

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Achievements for PvE-Appearences:

1. 
   
2. Tier 1: So Hot Right Now (Classic, [zone=2717])
3. 
   
4. Tier 2: Dress in Lairs (Classic, [zone=2677])
5. 
   
6. Tier 2.5: Accessor-Eyes (Classic, [zone=3428])
7. 
   
8. Tier 4: Outlandish Style (Bc, [zone=3457], [zone=3923] and [zone=3836])
9. 
   
10. Tier 5: Merely a Set (Bc, [zone=3607] and [zone=3845])
11. 
    
12. Tier 6: Black is the New Black (Bc, [zone=3959] and [zone=3606])
13. 
    
14. No Tier: Suns Out, Thori'dals Out (Bc, [zone=4075]) (You are here)
15. 
    
16. Tier 7: Undying Aesthetic (Northrend, [zone=3456])
17. 
    
18. Tier 8: Mogg-Saron (Northrend, [zone=4273])
19. 
    
20. Tier 9: Style of the Crusader (Northrend, [zone=4722])
21. 
    
22. Tier 10: Winter Catalog (Northrend, [zone=4812])
23. 
    
24. Tier 11: Glamour of Twilight (Cata, [zone=5334], [zone=5638] and [zone=5094])
25. 
    
26. Tier 12: Hot Couture (Cata, [zone=5723])
27. 
    
28. Tier 13: Wardrobe of the Old Gods (Cata, [zone=5892])
29. 
    
30. Tier 14: Sha of Fabulous (MoP, [zone=6297] and [zone=6067])
31. 
    
32. Tier 15: Thunderwear (MoP, [zone=6622])
33. 
    
34. Tier 16: Yaass'shaarj (MoP, [zone=6738])
35. 
    
36. Tier 17: Make it W-orc W-orc (Draenor, [zone=6967] and [zone=6996])
37. 
    
38. Tier 18: Extreme Makeover: Fel Edition (Draenor, [zone=7545])
39. 
    
40. Tier 19: That's So Last Millennium (Legion, [zone=8025])
41. 
    
42. No Tier: Can I Get A Helya (Legion, [zone=8440], you want the Ensemble)
43. 
    
44. Tier 20: Retro Trend (Legion, [zone=8524])
45. 
    
46. Tier 21: Argussy Up (Legion, [zone=8638])
47. 
    

If you didn't get the achievement after purchasing the last piece of gear just transmog the Sunwell set under "sets" tab and it should give you the achievement after you hit apply.