This is unlocked at Maruuk Centaur Renown 22.
Damaging a mob that is the singular target of a grand hunt objective (e.g. [npc=195417], [npc=193311], [npc=193341]) will give you the [spell=376283] buff for 30 sec, and the [spell=385742] debuff for 90 sec. While the debuff is active, Apex Hunter cannot proc again. As far as I can tell, the mob has to be the sole target of the objective - even if the objective is listed as 0/1 <something>, if you have to kill multiple mobs to get credit for it, Apex Hunter will not proc.
Quest
Hunting Tactics: Apex Hunter
A World of Warcraft quest in Ohn'ahran Plains. Facts and objectives from the current retail game data.
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Quest facts
LevelLevel 10-70
ZoneOhn'ahran Plains
Quest ID71032
The client quest POI data records no map location for this quest, so no map is shown.
Check whether you have already completed this quest
in-game: /run print(C_QuestLog.IsQuestFlaggedCompleted(71032))
Community notes from Wowhead · 1 comment
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Spell: Apex Hunter