Ancient Skinning Knife quest can be started in Zuldazar from drop item [item=161431] that you can get from skinning mobs in any zone.
You need Rank 2 and some skill level. I was able to pick up the item after ~100 skill level
After you farmed the item, just bring the item back to [npc=122699] skinning trainer in Dazar'alor
Ancient Skinning Knife video: https://www.youtube.com/watch?v=9yYQBnnGRhs
All the BfA Horde Skinning Zandalari Skinning quests:
1
50-70
[spell=257147] Rank 2
[npc=122699]
https://youtu.be/mtbEMitBv2w
2
100
[spell=257148] Rank 3
[item=161431]
Drop any zone
https://youtu.be/9yYQBnnGRhs
3
100
[spell=257153] Rank 2
[npc=122699]
https://youtu.be/aT8PitCZl80
4
150
[spell=257154] Rank 3
[npc=122699]
[zone=9028]
https://youtu.be/2pp5ja-cncg
5
50-70
[spell=257150] Rank 2
[npc=122699]
https://youtu.be/01YCsdQ3E6Y
6
150
[spell=257151] Rank 3
[npc=122699]
https://youtu.be/Vp92KJbYkUk
Skill column is approximate level you need to have to get this quest. It can be lower, i provide here info of level i was able to pick up the quest.
Drop item can drop from skinning the related beast in any zone.
Alliance questchain info is here: [spell=265870]
Table with some good skinning farm spots under the spoiler.
Spoiler
Zuldazar
49.04 54.45
Gorillas
May be hard
https://youtu.be/vP6S9UM-jrw
Vol'dun
53.58 15.75
Hyenas
Good amount
https://youtu.be/ptIwrvi5P1I
Tiragarde Sound <- second best
58.47 47.27
Seals
Good amount
https://youtu.be/ZBWXyfxJLO8
Drustvar <- the best
66.01 42.29
Quillrats
Fast respawn
https://youtu.be/CEG4rwH21FU
Zuldazar <- second best
64.71 18.38
Serpents, eggs
Spawn from eggs
https://youtu.be/VLvWZAmODGI
Vol'dun
39.33 63.01
Saurolisks
Average
https://youtu.be/FP38FNI1Y90
Drustvar
65.42 39.85
Saurolisks
Fast respawn
https://youtu.be/Ms5pY5QAeNk
Tiragarde Sound
44.10 17.89
Saurolisks
Average
https://youtu.be/OBLlqti4L1k
Nazmir <- the best
64.51 66.02
Razorjaw
Huge amounts
https://youtu.be/YdND9jUiqZ0
/way Zuldazar 49.04 54.45 Gorilla Gorge Coarse Leather farm
/way Vol'dun 53.58 15.75 Bouldered Bluffs Coarse Leather farm
/way Tiragarde Sound 58.47 47.27 Umber Shore Coarse Leather farm
/way Drustvar 66.01 42.29 Hawthorne's Plot Coarse Leather farm
/way Zuldazar 64.71 18.38 Rootway Shimmerscale farm
/way Vol'dun 39.33 63.01 Whistlebloom Oasis Shimmerscale farm
/way Drustvar 65.42 39.85 Drustvar Shimmerscale farm
/way Tiragarde Sound 44.10 17.89 Westwind Weald Shimmerscale farm
/way Nazmir 64.51 66.02 The Shattered River Shimmerscale farm